Pyrimidine, an Intermediate State Molecule?
نویسندگان
چکیده
منابع مشابه
Reaction of enzyme-bound 5-deazaflavin with peroxides. Pyrimidine ring contraction via an epoxide intermediate.
Reaction of peroxides with 5-deazaflavin bound to glucose oxidase, lactate oxidase, or D-amino acid oxidase results in the formation of 5-deazaflavin 4a, 5-epoxide. The reaction of D-amino acid oxidase with m-chloroperoxybenzoate is an exception since the reagent reacts rapidly with the protein moiety to form m-chlorobenzoate which then binds noncovalently near the unmodified coenzyme. Epoxide ...
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The H, system has excited much mterest both theoretically [l] and experimentally [2]. In particular It has been used to study elastic, inelastic and reacttve scattermg. The H3 molecule has been observed in an excited Rydberg state [3], a Bndtng confirmed by ab initio calculation [4,5], but as yet we know of no experimental evidence for it in its electronrc ground state. The ground-state potenti...
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ژورنال
عنوان ژورنال: Laser Chemistry
سال: 1986
ISSN: 0278-6273,1476-3516
DOI: 10.1155/lc.5.339